2-Methyl-2-butene

2-Methyl-2-butene[1][2][3]
Names
Preferred IUPAC name
2-Methylbut-2-ene
Other names
β-Isoamylene
Trimethylethylene
2-Methyl-2-butene
Isoamylene
Identifiers
CAS Number
  • 513-35-9 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 10113 checkY
ECHA InfoCard 100.007.416 Edit this at Wikidata
PubChem CID
  • 10553
UNII
  • HR68LQ4T3X checkY
UN number 2460
CompTox Dashboard (EPA)
  • DTXSID8027165 Edit this at Wikidata
InChI
  • InChI=1S/C5H10/c1-4-5(2)3/h4H,1-3H3 checkY
    Key: BKOOMYPCSUNDGP-UHFFFAOYSA-N checkY
  • InChI=1/C5H10/c1-4-5(2)3/h4H,1-3H3
    Key: BKOOMYPCSUNDGP-UHFFFAOYAE
  • C(=C(\C)C)\C
Properties
Chemical formula
C5H10
Molar mass 70.1329 g/mol
Appearance Colorless liquid
Odor Sweet
Density 0.662 g/cm3
Melting point −134 °C (−209 °F; 139 K)
Boiling point 39 °C (102 °F; 312 K)
Solubility in water
Slightly soluble
Solubility in alcohols, ether Miscible
Magnetic susceptibility (χ)
-54.14·10−6 cm3/mol
1.385
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Mildly toxic
Flash point < −45 °C (−49 °F; 228 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
Chemical compound

2-Methyl-2-butene, 2m2b, 2-methylbut-2-ene, also beta-isoamylene is an alkene hydrocarbon with the molecular formula C5H10.

Used as a free radical scavenger in trichloromethane (chloroform) and dichloromethane (methylene chloride). It is also used to scavenge hypochlorous acid (HOCl) in the Pinnick oxidation.

John Snow, the English physician, experimented with it in the 1840s as an anesthetic, but stopped using it for unknown reasons.[4]

See also

References

  1. ^ Dean's Handbook of Organic Chemistry, 2nd Edition.
  2. ^ "Safety (MSDS) data for 2-methyl-2-butene". Archived from the original on 2009-05-14. Retrieved 2009-03-24.
  3. ^ PubChem
  4. ^ Caton, Donald (2000). "John Snow's practice of obstetric anesthesia". Anesthesiology: The Journal of the American Society of Anesthesiologists. 92 (1): 247–252. doi:10.1097/00000542-200001000-00037. PMID 10638922.
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