Barium hexaboride

Barium hexaboride
Names
IUPAC name
Barium boride
Other names
Barium hexaboride
Identifiers
CAS Number
  • 12046-08-1
ECHA InfoCard 100.031.774 Edit this at Wikidata
PubChem CID
  • 6336903
CompTox Dashboard (EPA)
  • DTXSID501014267 Edit this at Wikidata
InChI
  • InChI=1S/6B.Ba
    Key: DBNPLCUZNLSUCT-UHFFFAOYSA-N
Properties
Chemical formula
BaB6
Molar mass 202.193 g/mol
Appearance Black, cubic substance
Density 4.36 g/cm3
Melting point 2,270 °C (4,120 °F; 2,540 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound

Barium hexaboride is a hard material with a high melting point.[1] It can be formed by passing a barium vapour at >750 °C over boron crystals:

Ba + 6B → BaB6

However, it can also be formed by reacting barium chloride with boron in two stages: firstly at 900 °C for 30 minutes and then at 1,500 °C for 60 minutes.

Potential applications

Barium hexaboride has been considered as a candidate for use in hot-cathode electron guns.

References

  1. ^ Massidda, S.; Monnier, R.; Stoll, E. (October 2000). "Electronic structure of barium hexaboride". The European Physical Journal B. 17 (4): 645–649. Bibcode:2000EPJB...17..645M. doi:10.1007/s100510070103. ISSN 1434-6028.
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Barium compounds
  • BaB6
  • Ba(BO2)2
  • BaBr2
  • Ba(BrO3)2
  • Ba(CH3CO2)2
  • Ba(C5H7O2)2
  • Ba(ClO)2
  • BaC2
  • BaCO3
  • BaC2O4
  • Ba(ClO3)2
  • BaClF
  • Ba(ClO4)2
  • Ba(CN)2
  • BaCl2
  • BaCrO4
  • BaF2
  • BaFeO4
  • BaFe2O4
  • BaH2
  • BaI2
  • Ba(IO3)2
  • BaMnO4
  • Ba(MnO4)2
  • Ba(N3)2
  • Ba(NO2)2
  • Ba(NO3)2
  • BaO
  • BaO2
  • Ba(OH)2
  • Ba(PO3)2
  • BaS
  • BaSe
  • BaSeO4
  • Ba(SCN)2
  • BaSO3
  • BaSO4
  • BaRuO3
  • BaSnO3
  • BaTiO3
  • Ba2TiO4
  • BaWO4
  • BaZnGa
  • Sr2Ba1-xNb2O6
  • YBa2Cu3O7-x
  • BaGeF6
  • BaSiF6
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Borides Bxy-
BxHy He
Li Be B C N O F Ne
Na MgB2 AlB2
AlB12
SiBx P S Cl Ar
K CaB4
CaB6
ScB12 TiB2 V CrB Mn FeB4
FexBy
CoxBy Ni3B
Ni2B
Cu Zn Ga Ge As Se Br Kr
Rb SrB6 YBx ZrB2 NbB2 Mo Tc RuBx Rh Pd Ag Cd In Sn Sb Te I Xe
Cs BaB6 * LuB4
LuB6
HfB2 TaBx WxBy ReB2 OsBx Ir Pt Au Hg Tl Pb Bi Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* LaB4
LaB6
CeB4
CeB6
PrB4
PrB6
NdB4
NdB6
Pm SmB4
SmB6
EuB6 GdB4
GdB6
TbB4
TbB6
DyB4
DyB6
HoB4
HoB6
ErB4
ErB6
TmB4
TmB6
YbB4
YbB6
** Ac Th Pa UB2 Np PuBx Am Cm Bk Cf Es Fm Md No
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